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Telluride (chemistry) : ウィキペディア英語版
Telluride (chemistry)

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The telluride ion is the anion Te2− and its derivatives. Telluride is member of the fifth period of the periodic table, containing the dianions O2−, S2−, and Se2− (see chalcogenide).〔Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.〕
The telluride anion is formed from the reduction of the tellurium metal. The redox potential of pure Te metal is fairly negative, -1.14 V.〔("Standard Reduction Potentials ), Indiana University.〕
:Te(s) + 2 e ↔ Te2−
The acid hydride of tellurium, hydrogen telluride, H2Te, is unstable compound that decomposes to tellurium metal. It is strongly acidic, dissociating into hydrogen telluride ion (HTe) in aqueous solutions. Like its sulfide and selenide counterparts, the Te2− anion only exists in aqueous solutions in basic conditions.
==Organic tellurides==
''Tellurides'' also describe a class of organotellurium compounds formally derived from Te2−. An illustrative member is dimethyl telluride, which results from the methylation of telluride salts:
:2 CH3I + Na2Te → (CH3)2Te + 2 NaI
Dimethyl telluride is formed by the body when tellurium is ingested . Such compounds are often called telluroethers because they are structurally related although the length of the C-Te bond is much longer than a C-O bond. C-Te-C angles tend to be closer to 90°.〔Reid, G., et al. ''Journal of Organometallic Chemistry'', 642 (2002) 186– 190.〕

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